选择离子流动管质谱法测定大蒜酶解液顶空中17种有机硫化合物 |
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引用本文: | 黄雪松,吕梦莎.选择离子流动管质谱法测定大蒜酶解液顶空中17种有机硫化合物[J].分析化学,2012(2):309-312. |
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作者姓名: | 黄雪松 吕梦莎 |
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作者单位: | 暨南大学食品科学与工程系 |
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基金项目: | 国家自然科学基金(No.31171722);公益性行业(农业)科研专项经费(No.200903018)资助 |
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摘 要: | 采用选择离子流动管质谱(SIFT-MS)法,顶空取样后,以H3O+,NO+或O2+为初始离子,定量分析了17种大蒜酶解液挥发性有机硫化合物。结果表明:有机硫化合物主要为二烯丙基硫醚、甲基烯丙基硫醚、硫代亚磺酸酯和硫醇,其中二烯丙基二硫醚浓度为137 g/m3,二烯丙基三硫醚浓度为13.4 g/m3,甲基烯丙基二硫醚浓度为8.98 g/m3,它们分别占17种有机硫化合物总含量的77.3%,7.58%和5.08%(相对含量);本研究采用顶空取样方法测出大蒜素的浓度为5.63 g/m3,相对含量为3.20%。
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关 键 词: | 选择离子流动管质谱 大蒜 酶解 有机硫化合物 大蒜素 |
Determination of 17 Organo-Sulphur Compounds in Headspace of Hydrolysates of Garlic Pulpy by Selected Ion Flow Tube-Mass Spectrometry |
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Institution: | Huang Xue-Song,Lü Meng-Sha(Department of Food Science and Engineering,Jinan University,Guangzhou 510632) |
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Abstract: | Selected ion flow tube mass spectrometry(SIFT-MS) method was used to determine the 17 organo-sulphur compounds in the headspace of the hydrolysates of garlic pulpy after headspace sampling,with H3O+,NO+ and O2+ as the precursory ions.The results showed that the 17 organo-sulphur compounds were mainly diallyl sulfides,allyl methyl sulfides,thiosulfinates and thiol.The concentration of diallyl disulfide,diallyl trisulfide and allyl methyl disulfide was 137,13.4 and 8.98 g/m3(relative amount),respectively.Their percentage to total amout of 17 organo-sulphur compounds was 77.34%,7.58% and 5.08%,respectively.The concentration of allicin was 5.63 g/m3 through headspace sampling,with relative amount of 3.20%. |
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Keywords: | Selected ion flow tube-mass spectrometry Garlic Hydrolysates Organo-sulphur compounds Allicin |
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