On the supposed equilibrium Ph6Pb2Ph4Pb+Ph2Pb in solution |
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Authors: | Gualtiero Plazzogna Valerio Peruzzo Giuseppe Tagliavini |
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Affiliation: | Istituto di Chimica Analitica, Universitá di Padovo, Via Marzolo, 1, 35100 Padova Italy |
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Abstract: | The reaction between pentadeuteriophenyllithium and hexaphenyldilead combined with new measurements of isotopic exchange between Ph6Pb2 (labelled with RaD) and Ph4Pb, have shown that the dilead compound is undissociated in solution. These results cast doubt upon the previously reported equilibrium: Ph6Pb2Ph4Pb+Ph2Pb. |
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