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Kinetic and mechanistic studies of the iridium(III) catalyzed oxidation of sulphanilic acid by diperiodatocuprate(III) in aqueous alkaline medium
Authors:Deepak S. Munavalli   Praveen N. Naik   Shivamurti A. Chimatadar  Sharanappa T. Nandibewoor
Affiliation:(1) Department of Catalysis Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, PR China;(2) Xinao New-energy (Beijing) Science & Technology Corporation, Beijing, 100176, China
Abstract:The effect of La2O3, K2O and Li2O on the properties and catalytic performance of silica-supported nickel catalysts for the hydrogenation of m-dinitrobenzene was investigated. The catalysts promoted with La2O3, Li2O and K2O showed better catalytic performance than the catalyst without promotion, especially the ones co-promoted with La2O3 and K2O or Li2O.
Keywords:Hydrogenation   m-dinitrobenzene  nickel catalyst  promoter
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