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Regioselectivity of Friedel-Crafts acylation of aromatic compounds with several cyclic anhydrides
Authors:Iwao Hashimoto  Takatoshi Kawaji  Florin D Badea  Tsuyoshi Sawada  Shuntaro Mataka  Masashi Tashiro  Gouki Fukata
Institution:1. Department of Industrial Chemistry, Wakayama National College of Technology, Noshima 77, Nadamachi, 649-15, Goboh, Wakayama, Japan
2. Institute of Advanced Material Study, Kyushu University, 6-1 Kasuga Koh-en, Fukuoka 816, Kasuga, Japan
3. Department of Food Science and Technology, Faculty of Engineering, Toa University, 2-1, Ichinomiyagakuencho, 751, Shimonoseki, Yamaguchi, Japan
Abstract:The Friedel-Crafts acylations of various aromatic compounds with cyclic anhydrides such as 2-(p-substituted phenyl)butanedioic, 3-phenylpentanedioic and homophathlic anhydrides were carried out under various conditions in order to obtain informations about the regioselectivity of the ring opening of the cyclic anhydrides and about the possible reaction pathways in the acylations.
Keywords:
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