Asymmetric Diels-Alder reaction between acrylates and cyclopentadiene in the presence of chiral catalysts |
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| Authors: | E. G. Mamedov |
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| Affiliation: | (1) Institute of Petrochemical Processes, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan |
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| Abstract: | Asymmetric Diels-Alder reaction between cyclopentadiene and alkyl and cycloalkyl acrylates in the presence of new chiral catalysts, BBr3·MentOEt, AlCl2OMent, BBr2OMent, and BBr(OMent)2, was studied. Optically active bicyclo[2.2.1]hept-2-ene-5-carboxylates were synthesized. The influence of the reaction conditions on the total and optical yields and on the stereoselectivity of the adducts synthesized was examined. |
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