Electrochemical model of alkane oxidation by cytochrome P-450 |
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Authors: | A. M. Khenkin and A. E. Shilov |
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Affiliation: | (1) Institute of Chemical Physics, 142432 Chernogolovka, USSR |
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Abstract: | Catalytic oxidation of alkanes to alcohols and ketones was shown to take place in an electrochemical cell with iron porphyrin deposited on a graphite cathode. The oxidation mechanism was assumed to be similar to that of cytochrome P-450 action.
                                                                                          ,                        .          ,                                                  P-450.
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