Study of magnetic after-effect in magnesium manganese ferrites

The magnetic after-effect caused by the diffusion of electrons was studied in detail in MnMg ferrites of the series Mg_xMn_1.15–xFe_1.85O₄₊; the comparative measurements were also carried out on a sample of MgFe₂O₄₊₍<0). By combining the two methods, (a) investigation of the disaccommodation of initial permeability at different temperatures and (b) measurement of the displacement of the maximum of the temperature dependence tan with the frequency, it was possible to study the relaxation processes whose time constants lay between 0.5 sec and several hours, or between 10^–4 to 10^–7 sec. It was found that the processes taking place at low temperatures and studied by method (a) differ from those observed at high temperatures by method (b), particularly in the lower activation energies and greater dispersion of the time constants. In addition to these two main relaxation processes a weak relaxation superposed over the main disaccommodation was found in ferrites with non-zero content of manganese. An analysis of the intensity of different relaxation effects showed the participation of Mn ions in these relaxation effects and it was found that both main relaxations are probably equivalent as regards the final steady state, to the creation of which they lead; they differ however in the mechanism of electron diffusion by which this state is realized. The main features of the different diffusion mechanisms are discussed.

---

-

, , MnMg Mg_xMn_1.15–xFe_1.85O₄₊. MgFe₂O_{4+ (}<0). ()- , () tg , , 0,5 sec , 10^–4–10^–7 sec. , , () , , (), , , . , . Mn , , , , , ; , , , . .

---

---

In conclusion the author thanks Dr. J. Bro and K. Závta for valuable discussion and F. Vilím for carefully carrying out the measurements.