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Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand
Authors:Stefanelli Manuela  Nardis Sara  Tortora Luca  Fronczek Frank R  Smith Kevin M  Licoccia Silvia  Paolesse Roberto
Institution:Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, via della Ricerca Scientifica 1, 00133 Rome, Italy.
Abstract:Mono- and di-substituted β-nitro derivatives have been obtained from the reaction of ttcorrFeCl with sodium nitrite in refluxing DMF. This result is unprecedented for iron corrolates and further evidences the non-innocent character of the corrole ligand.
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