Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand |
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Authors: | Stefanelli Manuela Nardis Sara Tortora Luca Fronczek Frank R Smith Kevin M Licoccia Silvia Paolesse Roberto |
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Institution: | Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, via della Ricerca Scientifica 1, 00133 Rome, Italy. |
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Abstract: | Mono- and di-substituted β-nitro derivatives have been obtained from the reaction of ttcorrFeCl with sodium nitrite in refluxing DMF. This result is unprecedented for iron corrolates and further evidences the non-innocent character of the corrole ligand. |
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