| d3(Re+4)和d4(Os+4)组态晶体能谱的配位场理论分析 |
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| 引用本文： | 韩延德,李伯符,朱玉奎,孙家锺.d3(Re+4)和d4(Os+4)组态晶体能谱的配位场理论分析[J].高等学校化学学报,1982,3(Z1):97. |
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| 作者姓名： | 韩延德 李伯符 朱玉奎 孙家锺 |
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| 作者单位： | 吉林大学理论化学研究所 |
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| 摘 要： | 本文根据文献4]提出的配位场理论方法,采用SLГSГtτ方案,对晶体K2PtCl6中Re+4(5d3)和Os+4(5d4)离子能谱进行全分析,考虑了全部d3和d4组态的静电作用能,正八面体场势能和旋轨偶合作用能,计算了能级随参数变化曲线,能谱理论计算结果与文献9-10]强场方案计算结果一致,但改正了前人对实验能谱指认不正确之处。
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| 收稿时间： | 1981-09-09 |
THE ANALYSIS OF THE LIGAND FIELD THEORY OF CRYSTAL SPECTRUM OF d3 (Re+4) AND d4(Os+4) CONFIGURATION |
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| Han Yande,Li Baifu,Zhu Yukui,Sun Chia-chung.THE ANALYSIS OF THE LIGAND FIELD THEORY OF CRYSTAL SPECTRUM OF d3 (Re+4) AND d4(Os+4) CONFIGURATION[J].Chemical Research In Chinese Universities,1982,3(Z1):97. |
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| Authors: | Han Yande Li Baifu Zhu Yukui Sun Chia-chung |
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| Institution: | Institute of Theoretical Chemistry, Jilin University, Changchun |
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| Abstract: | In this paper, a theoretical analysis of the spectra for the ions Re+4 (5d3) and Os+4(5d4) in K2PtCl6 crystal is performed by means of ligand field method proposed by Tang et al. Also, in the SLГSГtτ scheme of octahedral symmetry, the energy curves in terms of crystal field and spin-orbital parameters are worked out. The results of our analysis are in accord with those obtained via a strong field treatment by Dorain9-10], but some spectra terms which have been inadequately assigned by Dorain9-l0] are corrected. |
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