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Spectroscopic investigation of the plasma of a high-current diffuse discharge in He/Ar/CF2Cl2(CCl4) mixtures
Authors:A K Shuaibov
Abstract:Survey emission spectra in the region of 190–600 nm and time and service-life characteristics of a transverse nanosecond discharge in He/Ar/CF2Cl2(CCl4) mixtures at a pressure of 10–100 kPa are investigated. In the emission spectra, excited products of the decomposition of freons—C2(A−X), CN(B−X), Cl 2 * , C*, Cl*, and Cl+*— and the emission of ArF at λ=193 nm are revealed. The emissions of Cl 2 * at λ=258 nm and ArF at λ=193 nm were the most intense. The discharge in the He/Ar/CF2Cl2 mixture is a multiwave emission source with λ=258 nm Cl 2 * 193 nm ArF, and probably, 175 nm Arcl. It is of interest for applications in UV-VUV-range pulse photometry. The duration of the emission on Cl 2 * , ArF, ArI, ClI, and ClII transitions in the discharge in the Ar/CF2Cl2 mixture (P=10–20 kPa) was 200–300 nsec. With adding He and increasing pressure to 100 kPa the duration of the emission decreased by a factor of 1.5–2. The basic mechanisms of the formation of Cl2, ArF, and CN(B) molecules in the transverse-discharge plasma are considered. Uzhgorod State University, 46, Pidgirna Str., Uzhgorod, 294000, Ukraine. Translated from Zhurnal. Prikladnoi Spektroskopii, Vol. 66, No. 2, pp. 241–246, March–April, 1999.
Keywords:plasma  discharge  argon  freon
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