| Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesqnioxane |
| |
| 引用本文： | DING Han-ming ZHANG Da-wei LI Jiang KONG Ai-guo SHAN Yong-kui. Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesqnioxane[J]. 高等学校化学研究, 2007, 23(4): 388-390 |
| |
| 作者姓名： | DING Han-ming ZHANG Da-wei LI Jiang KONG Ai-guo SHAN Yong-kui |
| |
| 作者单位： | Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China |
| |
| 基金项目： | Supported by the National Natural Science Foundation of China（ No. 20273021 ）, the Key Project of Shanghai Science and Technology Commlttee（No. 05JC14070） and the Excellent Young Teachers Program of Ministry of Education. |
| |
| 摘 要： | A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, ^29Si NMR, UV-Vis, and XRD. Struc-tural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligo-silsesquioxane as building blocks and titanium as bridging atoms.[第一段]
|
| 关 键 词： | 钛-硅酸盐材料 复合材料 合成 性能 |
Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesqnioxane |
| |
| DING Han-ming,ZHANG Da-wei,LI Jiang,KONG Ai-guo,SHAN Yong-kui,. Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesqnioxane[J]. Chemical Research in Chinese University, 2007, 23(4): 388-390 |
| |
| Authors: | DING Han-ming ZHANG Da-wei LI Jiang KONG Ai-guo SHAN Yong-kui |
| |
| Abstract: | A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, ^29Si NMR, UV-Vis, and XRD. Struc-tural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligo-silsesquioxane as building blocks and titanium as bridging atoms. |
| |
| Keywords: | Polyhedral oligosilsesquioxane Synthesis Titanium-silicate material |
| 本文献已被 维普 等数据库收录！ |
