| 氧化偶联聚合方法合成电活性聚芳醚酮 |
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| 引用本文： | 马晓波,晁单明,崔丽莉,张万金.氧化偶联聚合方法合成电活性聚芳醚酮[J].高等学校化学学报,2006,27(12):2438-2440. |
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| 作者姓名： | 马晓波 晁单明 崔丽莉 张万金 |
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| 作者单位： | 吉林大学麦克德尔米德实验室,长春,130012 |
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| 基金项目： | 国家重点基础研究发展计划(973计划);国家自然科学基金 |
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| 摘 要： | 通过氧化偶联聚合方法成功地合成出电活性聚芳醚酮. 该反应条件温和, 操作简单, 室温下即可进行. 用红外光谱、核磁共振谱、高效凝胶渗透色谱、循环伏安、热失重、X射线衍射等技术对所合成的聚合物进行了表征, 并探讨了聚合物的性能.
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| 关 键 词： | 聚芳醚酮 电活性 氧化偶联聚合 |
| 文章编号： | 0251-0790（2006）12-2438-03 |
| 收稿时间： | 05 9 2006 12:00AM |
| 修稿时间： | 2006-05-09 |
Synthesis of Electroactive Poly(aryl ether ketone) via Oxidative Coupling Polymerization Method |
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| MA Xiao-Bo,CHAO Dan-Ming,CUI Li-Li,ZHANG Wan-Jin.Synthesis of Electroactive Poly(aryl ether ketone) via Oxidative Coupling Polymerization Method[J].Chemical Research In Chinese Universities,2006,27(12):2438-2440. |
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| Authors: | MA Xiao-Bo CHAO Dan-Ming CUI Li-Li ZHANG Wan-Jin |
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| Institution: | Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China |
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| Abstract: | A novel electroactive poly(aryl ether ketone), with fixed conjugated length of oligoaniline(phenyl-capped aniline tetramer) in the main chain, was successfully synthesized via oxidative coupling polymerization method. The structure of poly(aryl ether ketone) was systematically studied by Fourier-transform infrared( FTIR) spectra, 1H NMR, and X-ray powder diffraction(XRD). And its electrochemical behavior was studied by cyclic voltammetry(CV) measurement. It was found that the obtained poly(aryl ether ketone) bearing phenyl-capped aniline tetramer segments had a reversible electrochemical property in the cyclic voltammetry, which was the same as that of polyaniline. Moreover, the thermal properties of poly(aryl ether ketone) were evaluated by thermogravimetric analysis(TGA). |
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| Keywords: | Poly(aryl ether ketone) Electroactivity Oxidative coupling polymerization |
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