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Measuring maximum tensile strength of liquids at low stressing rates
Authors:A.S. Lubansky  R. BradP.R. Williams  D. DeganelloT.C. Claypole
Affiliation:a Multidisciplinary Nanotechnology Centre, Swansea University, Swansea SA2 8PP, United Kingdom
b Department of Engineering Science, University of Oxford, Parks Rd., Oxford OX1 3PJ, United Kingdom
c Welsh Centre for Printing and Coating, Swansea University, Swansea SA2 8PP, United Kingdom
Abstract:A technique is presented for determining the maximum tensile strength of a given fluid through the analysis of the break-up at the end of a capillary-thinning experiment. This technique allows the characterisation of the tensile strength, an important parameter for understanding cavitation, of a fluid at lower stressing rates than previous methods, such as bullet-piston apparatus. The method was validated by tests on a range of concentrations and molecular weights of polyethylene glycol, comparing the results with the values and behaviours observed from the bullet piston apparatus. Excellent agreement was observed between the two techniques, with quantitative differences corresponding to the differences in stressing rates. The results from the capillary break-up experiments were also used to investigate the effect of concentration and molecular-weight on tensile strength.
Keywords:Extensional rheology   Tensile strength   Cavitation   Bullet-piston
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