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A study on optical limiting properties of Eosin-Y and Eriochrome Black-T dye-doped poly (vinyl alcohol) composite film
Authors:K M Manikandan  A Yelilarasi  P Senthamaraikannan  S S Saravanakumar  Anish Khan  Abdullah M Asiri
Institution:1. Department of Physics, Kamaraj College of Engineering and Technology, Madurai, Tamil Nadu, India;2. Department of Mechanical Engineering, Kamaraj College of Engineering and Technology, Madurai, Tamil Nadu, India;3. Chemistry Department, King Abdulaziz University, Jeddah, Saudi Arabia;4. Center of Excellence for Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia
Abstract:A poly (vinyl alcohol) PVA/Eriochrome Black-T (EBT) dye, and PVA/Eosin-Y (EY) dye composite film was prepared using a solution casting process. The dye-doped composite polymer films were characterized by UV–vis spectroscopy. An optical band gap (Eg) of pure PVA reduced from 4.22?eV to 2.80?eV for PVA/EBT film and 2.14?eV for PVA/EY film respectively. This result indicates the occurrence of inter-molecular hydrogen bonding between the –OH functional group in PVA chains and sulfonate (EBT) and carboxyl group (EY) in dye molecules, respectively. Moreover, the experimental result of PVA/EBT and PVA/EY composite film showed the excellent properties of a large scale cut-off filter in the ultraviolet and visible range region.
Keywords:Poly (vinyl alcohol)  Eriochrome Black T dye  Eosin Y dye  optical properties
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