| Synthesis and Characteristics of a New Molybdoantimonate KSbMoO_5 |
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| 作者姓名： | WANG Yong-Jinga b ZHANG Han-Huia b① HUANG Chang-Canga b YU Xiao-Honga SUN Qiao-Zhena SUN Rui-Qinga a |
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| 作者单位： | WANG Yong-Jinga，b ZHANG Han-Huia，b① HUANG Chang-Canga，b YU Xiao-Honga SUN Qiao-Zhena SUN Rui-Qinga a (Department of Chemistry，Fuzhou University，Fuzhou 350002，China) b (State Key Laboratory of Structural Chemistry，Fuzhou 350002，China) |
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| 摘 要： | 1 INTRODUCTION Great efforts have been made for the discovery of microporous solids due to their rich structural chemi- stry and wide applications in some commercial pur- poses as ion exchanger, absorbent, and catalyst1]. Since many properties of porous materials depend on their composition and architecture, recent attention has been paid to incorporating other main group and tra- nsition metals into open frameworks, and plenty of materials are reported to contain polyhedra, such as X…
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| 关 键 词： | 热液合成 晶体结构 KSbMoO5 X射线衍射分析 钼 |
Synthesis and Characteristics of a New Molybdoantimonate KSbMoO5 |
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| WANG Yong-jing,ZHANG Han-hui,HUANG Chang-cang,YU Xiao-Hong,SUN Qiao-Zhen,SUN Rui-qing.Synthesis and Characteristics of a New Molybdoantimonate KSbMoO_5[J].Chinese Journal of Structural Chemistry,2005,24(6):651-654. |
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| Authors: | WANG Yong-jing ZHANG Han-hui HUANG Chang-cang YU Xiao-Hong SUN Qiao-Zhen SUN Rui-qing |
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| Abstract: | A two-dimensional solid of KSbMoO5 has been synthesized by hydrothermal methods and structurally characterized by X-ray crystallography. It crystallizes in the monoclinic system, space group P21/c with a = 9.2084(7), b = 11.3155(7), c = 5.6691(3) (A), β = 107.624(3)°, V = 562.98(6) (A)3, Z = 4, Mr = 336.79, Dc = 3.974 g/cm3, F(000) = 608 and ((MoKα = 7.697 mm-1. The final R = 0.0496 and wR = 0.1294 for 888 observed reflections with I > 2σ(Ⅰ). The structure is built up of SbMoO5-layers, between every two of which sodium cations are located. |
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| Keywords: | molybdoantimonate crystal structure hydrothermal synthesis |
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