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Iron-facilitated direct oxidative C-H transformation of allyl arenes to alkenyl aldehydes |
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| Authors: | Teng Wang Shi-Kai XiangChong Qin Jun-An MaLi-He Zhang Ning Jiao |
| Affiliation: | a Department of Chemistry, Tianjin University, Tianjin 300072, China b State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Xue Yuan Rd. 38, Beijing 100191, China c State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China |
| Abstract: | A direct oxidative approach to alkenyl aldehydes from allyl arenes via allyl sp3 C-H functionalization was disclosed. An inexpensive iron catalyst was employed to facilitate this transformation. The mechanistic studies indicate that the cleavage of the allyl sp3 C-H bond is involved in the rate-determining step. |
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