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Heats of adsorption of hydrocarbons on solid surfaces
Authors:Z. T. Dmitrieva  I. V. Bylina
Affiliation:(1) Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Akademicheskii prosp., 634021 Tomsk, Russian Federation
Abstract:
The integral heats of the interphase interaction of liquid aliphatic and aromatic hydrocarbons with fibers and powders of polyacrylonitrile and polypropylene, clay, and sandstone at 293 and 303 K were evaluated microcalorimetrically. The relationships between the heat of adsorption of hydrocarbons and the sorbate : adsorbent mass ratio were obtained. The heat and time needed for the interaction of hydrocarbons with the solid surfaces to reach equilibrium depend mainly on the adsorbent structure.
Keywords:adsorption  heat of adsorption  aliphatic and aromatic hydrocarbons  polyacrylonitrile and polypropylene fibers  powders  clay  sandstone
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