|
|||||
|
|
Phosphorylation of Allyl Halides with White Phosphorus |
|
| Authors: | Svetlana Malysheva Boris Sukhov Nina Gusarova Svetlana Shaikhudinova Tat'yana Kazantseva Natal'ya Belogorlova |
| Affiliation: | A. E. Favorsky Irkutsk Institute , Chemistry of the Russian Academy of Sciences , Irkutsk, Russia |
| Abstract: | White phosphorus reacts with allyl bromide in the system KOH-dioxane-H 2 O at room temperature to form tris(propen-2-yl), bis(propen-2-yl)(E-propen-1-yl), and bis(E-propen-1-yl)(propen-2-yl)phosphine oxides in a total quantitative yield, their molar ratio being 1:0.5:0.1. |
| Keywords: | Allyl Halides Phosphorylation Propenylphosphine Oxides White Phosphorus |