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Preparation of Metallaiminophosphoranes and Their Reactivity |
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| Authors: | Kazuyuki Kubo Hiroshi Nakazawa Hiroyasu Inagaki Tomoyuki Miyake Tsutomu Mizuta Katsuhiko Miyoshi |
| Institution: | Hiroshima University , Japan |
| Abstract: | Treatment of Cp*(CO) 2 M{P(NHPh)(OMe) 2 }]PF 6 (M = Fe and Ru) with NaNH 2 gives metallaiminophosphoranes, Cp*(CO) 2 M{P(NPh)(OMe) 2 }. The x-ray structures and reactivity of the complexes are reported. |
| Keywords: | Iron Metallaiminophosphorane P--N Double Bond Reactivity Ruthenium x-ray Structure |