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Synthesis of Functionalized Tetrahydrofurans from Hydroxy Sulfinyl Dienes |
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| Authors: | Roberto Fernández de la Pradilla Alejandro Castellanos Mercedes Ureña Alma Viso |
| Institution: | Instituto de Qúímica Or?anica , Consejo Superior de Investigationes Cientíyficas , Madrid, Spain |
| Abstract: | Hydroxy sulfinyl dienes yielded functionalized tetrahydrofurans through nucleophilic and metal-catalyzed epoxidations.1] Effective oxirane cleavage has been achieved in these systems and a formal synthesis of (?)-Kumausallene is reported. |
| Keywords: | Asymmetric synthesis epoxides sulfoxides tetrahydrofurans |