Chemoselective Oxidation of Benzylic Alcohols and Hydroquinones with bis-(2,4,6-Trimethylpyridinium) Dichromate (BTMPDC) as an Efficient and New Oxidizing Agent |
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Authors: | Lotfi Shiri Arash Ghorbani-Choghamarani |
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Institution: | Department of Chemistry, Faculty of Science , Ilam University , Ilam, Iran |
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Abstract: | A simple, efficient, and chemoselective oxidation of benzylic alcohols to the corresponding aldehydes and ketones and also hydroquinones to the benzoquinones using bis-(2,4,6-trimethylpyridinium) dichromate (BTMPDC) in acetonitrile is described. A good range of primary and secondary benzylic alcohols and a limited range of hydroquinones were selectively oxidized under reflux conditions in reasonable yields. |
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Keywords: | Alcohols bis-(2 4 6-trimethylpyridinium) dichromate hydroquinone oxidation |
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