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The Synthesis and Properties of Some Fluorinated Dialkyl Phosphoramidates |
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| Authors: | Christopher M Timperley Matthew J Waters |
| Institution: | Chemical and Biological Sciences , Defence Science and Technology Laboratory , Porton Down, Salisbury , Wiltshire , SP4 0JQ , UK |
| Abstract: | The synthesis and physical properties of the first fluorinated dialkyl phosphoramidates of structure (RCH 2 O) 2 P(O)NHCH 2 R F , where R = CH 3 , CF 3 or CCl 3 and R F = CF 3 or C 2 F 5 , are described. They were obtained by treatment of the respective dialkyl phosphorochloridates with trifluoroethylamine or pentafluoropropylamine in ether in the presence of triethylamine. |
| Keywords: | Bis(2 2 2-trichloroethyl)phosphorochloridate Bis(2 2 2-trifluoroethyl) Phosphorochloridate Dialkyl Phosphoramidate Dialkyl Phosphorochloridate Fluorinated Amine |