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High pressure and emission spectra of Eu3+ in L-EuBO3
Authors:B R Jovanić  E Antic-Fidancev
Institution:1. Institute of Physics , University of Belgrade , Centre of Experimental Physics, Laboratory for Multidisciplinary Research, PO Box 68, 11080 Zemun, Belgrade, Serbia brana@phy.bg.ac.yu;3. Laboratoire de Chimie Appliquée de l’Etat Solide CNRS UMR 7574 , ENSCP , 11 rue Pierre et Marie Curie, 75231, Paris Cedex 05, France
Abstract:Effects of the high pressure on the emission spectra of Eu3+-activated L-EuBO3 were considered at room temperature up to 100 kbar. The position of five 0–2 lines in the 5D07F2 transition region was determined. The pressure does not have the same effect on all these lines. In four of them, high pressure induced a red shift with different shift rates:+0.0022,+0.0035,+0.0034 and+0.0027 nm kbar?1, respectively, whereas in the last one, high pressure induced a blue shift with shift rate?0.0034 nm kbar?1. Possible reasons for the mentioned pressure effects on the line positions were considered.
Keywords:High pressure  Rare-earth  Fluorescence spectra
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