High pressure and emission spectra of Eu3+ in L-EuBO3 |
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Authors: | B R Jovanić E Antic-Fidancev |
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Institution: | 1. Institute of Physics , University of Belgrade , Centre of Experimental Physics, Laboratory for Multidisciplinary Research, PO Box 68, 11080 Zemun, Belgrade, Serbia brana@phy.bg.ac.yu;3. Laboratoire de Chimie Appliquée de l’Etat Solide CNRS UMR 7574 , ENSCP , 11 rue Pierre et Marie Curie, 75231, Paris Cedex 05, France |
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Abstract: | Effects of the high pressure on the emission spectra of Eu3+-activated L-EuBO3 were considered at room temperature up to 100 kbar. The position of five 0–2 lines in the 5D0→7F2 transition region was determined. The pressure does not have the same effect on all these lines. In four of them, high pressure induced a red shift with different shift rates:+0.0022,+0.0035,+0.0034 and+0.0027 nm kbar?1, respectively, whereas in the last one, high pressure induced a blue shift with shift rate?0.0034 nm kbar?1. Possible reasons for the mentioned pressure effects on the line positions were considered. |
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Keywords: | High pressure Rare-earth Fluorescence spectra |
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