New Chiral Ortho-P,S-Difunctionalized Aromatic Compounds |
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| Authors: | Mihaela Gulea Isabelle Abrunhosa Jozef Drabowicz Guillaume Grach Matthieu Hamel Serge Masson |
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| Affiliation: | 1. Laboratoire de Chimie Moléculaire et Thio-Organique, UMR-CNRS, Université–ENSICAEN , Caen, France;2. Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences , Lódz, Poland |
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| Abstract: | Abstract A new method to prepare enantioenriched sulfinates was developed to obtain optically active ortho-methylsulfinyl(phenylphosphonates). It consists of a diastereoselective oxidation of sulfenates to sulfinates. Additionally, preliminary results concerning the synthesis of ortho-phophonylated benzylic thiol derivatives via a new P═S to P═C [1,4]-rearrangement and a first synthetic application of these compounds are also described. |
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