Control of porosity geometry in amino acid derived nanoporous materials |
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Authors: | Perez Barrio Jorge Rebilly Jean-Noël Carter Benjamin Bradshaw Darren Bacsa John Ganin Alexey Y Park Hyunsoo Trewin Abbie Vaidhyanathan Ramanathan Cooper Andrew I Warren John E Rosseinsky Matthew J |
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Institution: | Department of Chemistry, University of Liverpool, Liverpool, UK. |
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Abstract: | Substitution of the pillaring ligand in the homochiral open-framework Ni(2)(L-asp)(2)(bipy)] by extended bipy-type ligands leads to a family of layer-structured, homochiral metal-organic frameworks. The 1D channel topology can be modified by the nature of the organic linker, with shape, cross-section and the chemical functionality tuneable. In addition, the volume of these channels can be increased by up to 36 % compared to the parent Ni(2)(L-asp)(2)(bipy)]. The linker 1,4-dipyridylbenzene (3rbp) gives access to a new layered homochiral framework Ni(2)(L-asp)(2)(3rbp)] with channels of a different shape. In specific cases, non-porous analogues with the linker also present as a guest can be activated to give porous materials after sublimation. Their CO(2) uptake shows an increase of up to 30 % with respect to the parent Ni(2)(L-asp)(2)(bipy)] framework. |
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Keywords: | amino acids chirality metal–organic frameworks porous materials |
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