Catalytic Asymmetric Inverse‐Electron‐Demand Hetero‐Diels−Alder Reactions |
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Authors: | Dr Mingsheng Xie Dr Lili Lin Prof?Dr Xiaoming Feng |
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Institution: | 1. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, China;2. (+86)28‐8541‐8249 |
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Abstract: | In this review, the recent developments in catalytic asymmetric inverse‐electron‐demand hetero‐Diels?Alder reaction, which is recognized as one of the most powerful routes to construct highly functionalized and enantioenriched six‐membered heterocycles, are described. The article is organized on the basis of different kinds of electron‐deficient heterodienes, including α,β‐unsaturated ketones/aldehydes, o‐benzoquinones, α,β‐unsaturated imines, N‐aryl imines, o‐benzoqinone imides, and other aza‐olefins. |
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Keywords: | asymmetric synthesis hetero-Diels− Alder reaction inverse-electron-demand cycloaddition heterocycles |
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