Protonation constant of salicylidene (N-benzoyl)glycyl hydrazone and its coordination behaviour towards some bivalent metal ions |
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Authors: | R K Lonibala T R Rao and R K Babita Devi |
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Institution: | (1) Department of Chemistry, Banaras Hindu University, 221 005 Varanasi;(2) Present address: Chemistry Department, Manipur University, 795 003 Canchipur |
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Abstract: | Protonation constant of an unsymmetrical Schiff base, salicylidene(N-benzoyl)glycyl hydrazone (SalBzGH), and formation constants
of its complexes have been determined potentiometrically at different temperatures in aqueous dioxane medium. Complexes of
SalBzGH with VO(IV), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) have been prepared. Elemental analyses, pH-metric,
molar conductance, magnetic susceptibility, electronic, IR, ESR, XRD (powder) and NMR studies have been carried out to study
the coordination behaviour of SalBzGH toward these metal ions. pH-metric and 1H NMR studies show the presence of two dissociable
protons in the ligand. IR and NMR spectra suggest the tridentate nature of the ligand, coordinating as a uninegative species
in the Mn(II) complex and as a dinegative species in all the other complexes. Presence of two different conformers of the
ligand at room temperature and stabilization of a single conformer upon complex formation have been established from1H NMR spectra of the metal-free ligand, Zn(II) and Hg(II) complexes recorded at 296 K. Electronic and ESR spectra indicate
highly distorted tetragonal geometry for VO(IV) and Cu(II) complexes. XRD powder patterns of the Zn(II) complexes are indexed
for an orthorhombic crystal system. |
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Keywords: | Salicylidene(N-benzoyl)glycyl hydrazone protonation constant NMR coordination behaviour |
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