| 六氰合铁酸锰铬修饰电极的制备及其电化学行为 |
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| 引用本文： | 张胜涛,韩晓燕,薛茗月.六氰合铁酸锰铬修饰电极的制备及其电化学行为[J].电化学,2007,13(3):334-338. |
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| 作者姓名： | 张胜涛 韩晓燕 薛茗月 |
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| 作者单位： | 重庆大学化学化工学院,重庆大学化学化工学院,重庆大学化学化工学院 重庆400044,重庆400044,重庆400044 |
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| 摘 要： | 应用循环伏安法在活化玻碳电极(GCE)表面制备六氰合铁酸锰铬(MnCrHCF)膜修饰电极(MnCrH-CF/GCE)并研究其电化学性质.探讨影响膜电沉积的因素,研究pH值以及不同支持电解质等制备条件对该修饰电极性能的影响,优化制备工艺,分析其反应机理.
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| 关 键 词： | 玻碳电极 六氰合铁酸锰铬 循环伏安法 |
| 文章编号： | 1006-3471（2007）03-0334-05 |
| 收稿时间： | 2006-12-03 |
| 修稿时间： | 2007-04-25 |
Preparation of Manganese/Chromium Hexacyanoferrate Modified Glassy Carbon Electrode and Its Electrochemical Behavior |
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| ZHANG Sheng-tao,HAN Xiao-yan,XUE Ming-yue.Preparation of Manganese/Chromium Hexacyanoferrate Modified Glassy Carbon Electrode and Its Electrochemical Behavior[J].Electrochemistry,2007,13(3):334-338. |
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| Authors: | ZHANG Sheng-tao HAN Xiao-yan XUE Ming-yue |
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| Institution: | College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China |
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| Abstract: | A film of poly(manganese/chromium hexacyanoferrate)(MnCrHCF)is formed on the glassy carbon electrode(GCE) by Cyclic Voltammetry scanning,and its electrochemical behavior was studied.Factors affecting the electro-deposition of the film such as pH values and sustaining electrolytes,were discussed.And mechanism of the reaction was investigated. |
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| Keywords: | glassy carbon electrode manganese/chromium hexacyanoferrate cyclic voltammetry |
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