Thorium(IV) and uranium(IV) carbamates |
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| Affiliation: | 1. MTA-DE Homogeneous Catalysis and Reaction Mechanisms Research Group, Egyetem tér 1, Debrecen H-4032, Hungary;2. University of Debrecen, Department of Inorganic and Analytical Chemistry, Egyetem tér 1, Debrecen H-4032, Hungary;3. Akzo Nobel Pulp and Performance Chemicals AB, Bohus S-445 80, Sweden;1. Lunenfeld-Tanenbaum Research Institute, Mount Sinai Hospital, Toronto, ON, Canada M5G 1X5;2. Department of Molecular Genetics, University of Toronto, Toronto, ON, Canada M5S 1A8;3. Department of Physiology, University of Toronto, Toronto, ON, Canada M5S 1A8;4. Center for Brain Science, Department of Physics, Harvard University, Cambridge, MA 02138, United States |
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| Abstract: | The insertion of CX2 (X = O, S, Se) and of COS into the metal-nitrogen bonds of thorium(IV) and uranium(IV) dialkylamides yields the corresponding carbamates. The infrared and 1H-NMR spectra of these products are discussed. |
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