Some aspects of the reactivity of amino acids coordinated to metal ions |
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| Affiliation: | 1. Department of Chemistry, Inorganic Section, Jadavpur University, Kolkata 700 032, India;2. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße, 35032 Marburg, Germany;1. Gold Catalysis Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, PR China;2. Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo 192-0397, Japan |
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| Abstract: | Some features of the reactivity of the amino acids coordinated to metal ions are reviewed. Special emphasis is given to the formation and the hydrolysis of esters and peptides, to some reactions of complexes of amino acids Schiff bases, to aldol condensation and to isotopic exchange and racemization at the α-carbon atom. The change of reactivity which follows the coordination to metal atoms and some possible references to inorganic biochemistry are also outlined. |
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