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Sn3O4 single crystal nanobelts grown by carbothermal reduction process
Authors:Cleocir Jose Damaschio  Olivia M. Berengue  Daniel G. Stroppa  Ricardo A. Simon  Antonio J. Ramirez  Wido Herwig Schreiner  Adenilson J. Chiquito  Edson R. Leite
Affiliation:1. Laboratório Interdisciplinar de Eletroquímica e Cerâmicas, Departamento de Química, Universidade Federal de São Carlos, CEP 13565-905, CP 676, São Carlos, São Paulo, Brazil;2. Nano Lab—Departamento de Física, Universidade Federal de São Carlos, CEP 13565-905, CP 676, São Carlos, São Paulo, Brazil;3. Laboratório Nacional de Luz Síncrotron, CEP 13084-971, CP 6192, Campinas, São Paulo, Brasil;4. Laboratório de Superfícies e Interfaces, Universidade Federal do Paraná, CEP 81531-990, CP 19081, Curitiba, Paraná, Brazil
Abstract:
This article reports on the growth of single crystal Sn3O4 nanobelts and SnO by a carbothermal reduction process in two different regions of a furnace tube. Even though intermediate tin oxide compounds (Sn3O4) have been observed experimentally, the study of structures based on them is a challenging task. Characterization data allowed us to propose that Sn3O4 nanobelts grew by vapor–solid mechanism while SnO grew by self-catalyst vapor–liquid–solid mechanism. Electrical measurements of a single Sn3O4 nanobelt were performed at different temperatures, revealing undoped semiconductor characteristics.
Keywords:A1. Dendrites   A1. Nanostructures   A2. Growth from vapor   B1. Oxides   B2. Semiconducting materials
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