Transition Metal Ion-binding Properties of a 14-Membered N2O2S2- Macrobicyclic Ligand |
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| Authors: | ÜMMÜHAN OCAK HALIT KANTEKIN YA?AR GÖK H BASIR ?ENTÜRK |
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| Institution: | (1) Department of Chemistry, Faculty of Arts and Sciences, Karadeniz Technical University, 61080 Trabzon, Turkey |
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| Abstract: | The selective liquid–liquid extraction of various transition metal cations from the aqueous phase to the organic phase was carried out using a 14-membered N2O2S2-macrobicycle. Metal picrates such as Pb2+, Co2+, Zn2+, Ni2+,Cu2+ and Cd2+ were used in this extraction studies. It was found that the ligand showed moderate selectivity towards Pb2+ only among the other metals. The extraction constant (log K
ex) was determined to be 13.8 for Pb2+ complex. |
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| Keywords: | extraction constant liquid– liquid extraction N2O2S2-macrobicycle selective extraction transition metal cation |
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