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A general and efficient reduction of acyl chlorides to aldehydes by Sm(0)/Bu3P |
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| Authors: | Xueshun Jia Xiaotao Liu Peichao Zhao |
| Institution: | a Department of Chemistry, Shanghai University, Shanghai 200444, PR China b Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou 310028, PR China c State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, PR China |
| Abstract: | A facile and efficient reduction of aromatic and aliphatic acyl chlorides to their corresponding aldehydes in the presence of Sm(0)/Bu3P has been developed with broad scope. This method prevents over reduction of products, that is, the over-reduction of aldehydes to alcohols. |
| Keywords: | Aldehyde Acyl chloride Sm(0)/Bu3P Reduction |
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