The formation of novel 1,3-dioxolanes: atypical Baylis-Hillman reaction of a sesquiterpene lactone parthenin |
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Authors: | Bhahwal A. Shah Vijay K. Sethi Samar S. Andotra Ghulam N. Qazi |
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Affiliation: | a Regional Research Laboratory (CSIR), Canal Road, Jammu Tawi, 180 001, India b Guru Nanak Dev University, Amritsar 143 005, India |
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Abstract: | The Baylis-Hillman reaction of a sesquiterpene lactone parthenin with various aldehydes gave unexpected products containing a 1,3-dioxolane moiety. Both small aliphatic and aromatic aldehydes produced 1,3-dioxolanes, whereas higher aliphatic aldehydes produced normal Baylis-Hillman products. |
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