A novel one-pot conversion of amines to homologated esters in poly(ethylene glycol) |
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| Authors: | S Chandrasekhar G Pavan Kumar Reddy Ch Nagesh Ch Raji Reddy |
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| Institution: | Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | The first deaminative homologation of amines (-CH2NH2) to esters (-CH2CH2COOEt) in one-pot is reported. The reaction proceeds through, formation of an aldehyde from an amine in the presence of Pd/C as catalyst followed by Wittig reaction and catalytic hydrogenation using poly(ethylene glycol) as the solvent in one-pot. |
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| Keywords: | Palladium One-pot reaction Poly(ethylene glycol) Amines Esters |
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