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Ligand Mediated Morphology of the Two‐Dimensional Uranyl Aqua Sulfates [UO2(X)(SO4)(H2O)] [X = Cl– or (CH3)3NCH2COO]
Authors:Philip A Smith  Peter C Burns
Abstract:Two uranyl aqua sulfate compounds: (CH3)3NCH2COOH] UO2(Cl)(SO4)(H2O)] ( 1 ) and UO2((CH3)3NCH2COO)(SO4)(H2O) ( 2 ) were synthesized and their crystal structures were determined. The morphology changes between the two‐dimensional anionic structural unit of 1 and the neutral structural unit of 2 are examined, and the impact of their terminally coordinating ligands discussed.
Keywords:Uranyl  Betaine  Halide  Ionic liquid  Betainium  Uranium  Coordination
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