Mass spectra of the negative ions of some dioxanes |
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| Authors: | I. I. Furlei V. S. Shmakov D. L. Rakhmankulov S. S. Zlotskii |
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| Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation;(2) Research Institute of Small-Scale Products and Reagents, 75 ul. Ul'yanovykh, 450029 Ufa, Russian Federation |
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| Abstract: | It was established by mass spectrometry of negative ions that fragmentation of some 1,3- and 1,4-dioxanes proceeds through intermediate [M-H]− ions. The fragmentation pathway depends on the site of negative charge localization in these ions. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 11, pp. 2199–2201, November, 1999. |
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| Keywords: | substituted dioxanes resonance capture of electrons negative ions mass spectra fragmentation [M-H]− ions |
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