Vibrational spectra and structure ofN,N-dinitromethylamine |
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| Authors: | V G Avakyan V A Shlyapochnikov B S Fedorov V N Margolin V V Volkova |
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| Institution: | (1) A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 117912 Moscow, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation;(3) Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation;(4) Scientific Research Institute of Plant Protection Chemicals, 31 ul. Ugreshskaya, 109088 Moscow, Russian Federation |
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| Abstract: | The vibrational (IR and Raman) spectra ofN,N-dinitromethylamine were studied. The assignments of the bands were carried out using a comparison of spectra obtained in different aggregate states, invoking the results of normal coordinate analysis. The most probable symmetry of the molecule was shown to beC
s with a planar configuration of the N(NO2)2 moiety.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1503–1507, August, 1995. |
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| Keywords: | nitramines vibrational spectra N N-dinitromethylamine |
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