Electrochemical and electrocatalytic properties of meso-triphenylcorrole and its complexes with Mn(III), Co(III), Cu(III), and Zn(II) |
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Authors: | M I Bazanov N M Berezina D R Karimov D B Berezin |
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Institution: | 1. Ivanovo State University of Chemical Technology, F. Engelsa pr. 7, Ivanovo, 153000, Russia
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Abstract: | The method of cyclic voltammetry (CV) was used to compare electrochemical and electrocatalytic properties of meso-triphenylcorrole H3(ms-Ph)3Cor] and also its complexes with Mn(III), Co(III), Cu(III), and Zn(II) in 0.1M KOH. Metal-localized redox transitions are detected in the complexes of Mn (III ?? IV) and (III ?? II), Co (III ?? II), Cu (III ?? II). It is shown that the manganese complex features most effective catalytic properties in the reaction of molecular oxygen electroreduction. |
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