| Hydrothermal Synthesis,Crystal Structure and Properties of a Novel Polyoxometalate {[Cu~Ⅱ(1,10-phen)]_2[PMo~Ⅵ_(11)Mo~ⅤO_(40)]} [Cu~Ⅰ(C_8N_4H_6)(C_9H_6NO)(H_2O)] |
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| 引用本文： | 林欣蓉,陈建新,张力,兰婷燕,余友谊,柯志聪,胡丽珊,张治纯.Hydrothermal Synthesis,Crystal Structure and Properties of a Novel Polyoxometalate {[Cu~Ⅱ(1,10-phen)]_2[PMo~Ⅵ_(11)Mo~ⅤO_(40)]} [Cu~Ⅰ(C_8N_4H_6)(C_9H_6NO)(H_2O)][J].结构化学,2010,29(3):437-443. |
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| 作者姓名： | 林欣蓉 陈建新 张力 兰婷燕 余友谊 柯志聪 胡丽珊 张治纯 |
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| 作者单位： | College;Chemistry;Materials;Science;Fujian;Normal;University;State;Laboratory;Structural;Institute;Research;Structure;Matter;Chinese;Academy;Sciences; |
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| 基金项目： | supported by the Key Project of Chinese Ministry of Education (No 208066);;Natural Science Foundation of Fujian Province (2007J0216, U0750004);;Education Department of Fujian Province (JA07029);;State Key Laboratory of Structural Chemistry (No 20080053) |
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| 摘 要： | A new pseudo three-dimensional framework structure of the title compound {CuⅡ(1,10-phen)]2PMoⅥ11MoⅤO40]}CuⅠ(C8N4H6)(C9H6NO)(H2O)](1) has been prepared by the hydrothermal method for the first time and characterized by elemental analyses,X-ray single-crystal diffraction and IR spectra.1 consists of two building blocks,one {CuⅡ(1,10-phen)]2PMoⅥ11MoⅤO40]} and one CuⅠ(C8N4H6)(C9H6NO)(H2O)] coordinated group.Singlecrystal X-ray diffraction revealed that 1 crystallizes in the monoclinic system,space group P2/c with a=13.498(4),b=12.890(3),c=21.465(8),β=97.314o,V=3704(2)3,Mr=2693.61,Z=2,Dc=2.415 Mg/m3,μ=2.915 mm-1,F(000)=2562,S=1.009,the final R=0.0583 and wR=0.1406 for 5129 observed reflections with I2σ(I).Furthermore,compound 1 shows strong fluorescent properties in the solid state at room temperature.The electrochemical behavior of 1 has also been studied by cyclic voltammograms.
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| 关 键 词： | 水热合成 phen 晶体结构 荧光性能 多金属氧酸盐 X射线衍射分析 铜 标题化合物 |
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