| 三维超分子[Ni(hmt)2(SCN)2(H2O)2][Ni(SCN)2(H2O)4](H2O)2的自组装,晶体结构及磁性质(hmt=六次甲基四胺) |
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| 引用本文： | 李纲,朱玉,李林科,侯红卫,樊耀亭,杜晨霞.三维超分子[Ni(hmt)2(SCN)2(H2O)2][Ni(SCN)2(H2O)4](H2O)2的自组装,晶体结构及磁性质(hmt=六次甲基四胺)[J].无机化学学报,2002,18(5):537-540. |
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| 作者姓名： | 李纲 朱玉 李林科 侯红卫 樊耀亭 杜晨霞 |
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| 作者单位： | 1. 山西大学分子科学研究所,太原,030006;郑州大学化学系,郑州,450052
2. 郑州大学化学系,郑州,450052 |
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| 基金项目： | 留学人员归国基金资助项目，河南省自然科学基金资助项目(No.004030500)。 |
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| 摘 要： | Compound Ni(hmt)2(SCN)2(H2O)2]Ni(SCN)2(H2O)4](H2O)2 (hmt=hexamethylenetetramine) was pre-pared and structurally characterized by means of X-ray single crystal diffraction. The two neutral units Ni(hmt)2(SCN)2(H2O)2] and Ni(SCN)2(H2O)4] are joined together through hydrogen bonds N…H-O, O…H-O and S…H-O. In the solid state, the compound has three-dimensional network structure. The determination of its variable-temperature magnetic susceptibilities (5～300K) shows that the magnetic behavior obeys the Curie-Weiss law over the whole temperature ranges.
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| 关 键 词： | 自组装 超分子配合物 氢键 磁性 |
| 修稿时间： | 2001年10月11 |
Self-Assembly,Crystal Structure and Magnetic Properties of Three-Dimensional Supramolecular Complex [Ni(hmt)2(SCN)2(H2O)2][Ni(SCN)2(H2O)4](H2O)2(hmt=hexamet |
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| LI Gang,ZHU Yu,LI Lin-Ke,HOU Hong-Wei,FAN Yao-Ting and DU Chen-Xia.Self-Assembly,Crystal Structure and Magnetic Properties of Three-Dimensional Supramolecular Complex [Ni(hmt)2(SCN)2(H2O)2][Ni(SCN)2(H2O)4](H2O)2(hmt=hexamet[J].Chinese Journal of Inorganic Chemistry,2002,18(5):537-540. |
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| Authors: | LI Gang ZHU Yu LI Lin-Ke HOU Hong-Wei FAN Yao-Ting and DU Chen-Xia |
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| Institution: | Institute of Molecular Science, Shanxi University, Taiyuan 030006;Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052 and Department of Chemistry, Zhengzhou University, Zhengzhou 450052 |
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| Abstract: | Compound Ni(hmt) 2(SCN) 2(H2O) 2] Ni(SCN) 2(H2O) 4] (H2O) 2 (hmt = hexamethylenetetramine) was prepared and structurally characterized by means of X-ray single crystal diffraction.The two neutral units Ni(hmt)2variable-temperature magnetic susceptibilities (5 ～ 300K) shows that the magnetic behavior obeys the Curie-Weiss law over the whole temperature ranges. |
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| Keywords: | self-assembly supramolecular complex hydrogen bonds magnetic properties |
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