Crystal and molecular structure of [5,10,15,20-tetrakisphenyl-2-ethoxy-3-oxa-chlorinato]Ag(II) |
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| Authors: | Matthias?Zeller mailto:mzeller@cc.ysu.edu" title=" mzeller@cc.ysu.edu" itemprop=" email" data-track=" click" data-track-action=" Email author" data-track-label=" " >Email author,Allen?D.?Hunter,Jason?R.?McCarthy,Steven?H.?Capetta,Christian?Brückner |
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| Affiliation: | (1) Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, Ohio, 44555-3663;(2) Department of Chemistry, University of Connecticut, Unit 3060, Storrs, Connecticut, 06269-3060 |
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| Abstract: | ![]()
The silver(II) complex of the chlorin-like derivativev [5,10,15,20-tetrakisphenyl-2-ethoxy-3-oxa-chlorinato]Ag(II) (1Ag), formally formed by substitution of one pyrrolic subunit in silvermeso-tetraphenylporphyrin by one ethoxy-substituted hydrooxazole moiety, crystallizes in the tetragonal space groupI4/m witha = 13.4811(10) Å,c = 9.7361(13) Å, andZ = 2. The molecule, which is asymmetric, accommodates the high-symmetry space group by rotational disorder with the silver atom located on the four-fold axis. |
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| Keywords: | Porphyrin-analogs chlorins silver(II) complexes disorder |
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