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Are the prefactor anomalies in superionic conductors due to 1-D effects?
Authors:JB Boyce  JC Mikkelsen  BA Huberman
Institution:Xerox Palo Alto Research Center Palo Alto, California 94304, USA
Abstract:We have examined both the ionic conductivity and the NMR line narrowing in two channel-structured superionic conductors in the light of Richards' one-dimensional theory. For Li2Ti3O7 the ionic conductivity is not sufficiently anisotropic to explain the observed small NMR prefactor in terms of i-D effects. For β-LiAlSiO4 the NMR line narrowing in the crossover region does not yield the predicted large change in the activation energy given by the 1-D theory.
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