Are the prefactor anomalies in superionic conductors due to 1-D effects? |
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Authors: | JB Boyce JC Mikkelsen BA Huberman |
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Institution: | Xerox Palo Alto Research Center Palo Alto, California 94304, USA |
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Abstract: | We have examined both the ionic conductivity and the NMR line narrowing in two channel-structured superionic conductors in the light of Richards' one-dimensional theory. For Li2Ti3O7 the ionic conductivity is not sufficiently anisotropic to explain the observed small NMR prefactor in terms of i-D effects. For β-LiAlSiO4 the NMR line narrowing in the crossover region does not yield the predicted large change in the activation energy given by the 1-D theory. |
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