| 球笼烯（C_（60）／C_（70）载体钕系催化丁二烯聚合的研究 |
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| 引用本文： | 赵春英,杨海滨.球笼烯（C_（60）／C_（70）载体钕系催化丁二烯聚合的研究[J].高分子学报,1996(1):102-105. |
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| 作者姓名： | 赵春英 杨海滨 |
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| 摘 要： | 球笼烯（Ｃ_（６０）／Ｃ_（７０）载体钕系催化丁二烯聚合的研究赵春英，陈滇宝，仲崇祺，董文寰，徐玲，唐学明（青岛化工学院高分子材料系青岛２６６０４２）杨海滨，李明辉，邹广田（吉林大学超硬材料国家重点实验室长春１３００２３）关键词球碳载体钕系催化剂，聚丁...
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| 关 键 词： | 球碳载体钕系催化剂，聚丁二烯，催化活性 |
NOVEL FULLERENES C_(60)/C_(70) SUPPORTED NEODYNIUM CATALYST FOR BUTADIENE POLYMERIZATION |
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| Abstract: | or the first time,the fullerenes were applied to butadiene polymerization.The behavour of butadiene polymerization with novel fullerenes supported neodynium catalyst system were investigated.The effects of polymerization conditions on the catalytic activity were also examined.It revealed that the function of the fullerenes might is a ligand and asupporter and the mole ratio of Al/Nd and C60/Nd.The aging temperature and polymerization temperature had a relatively effect on catalytic activity.The catalyst system showed much better stability in catalytic activity for aging time and aging temperature as compared to general neodynium and nickle catalyst systms. |
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| Keywords: | Fullerenes C_(60)-supported neodynium catalyst Polybutadiene Catalytic activity |
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