Phospha-palladacycles and N-heterocyclic carbene palladium complexes: efficient catalysts for CC-coupling reactions |
| |
Authors: | Wolfgang A Herrmann Karl Öfele Denise v Preysing Sabine K Schneider |
| |
Institution: | Anorganisch-Chemisches Institut der Technischen Universität München, Lichtenbergstraße 4, 85747 Garching, Germany |
| |
Abstract: | Due to the great importance of palladium-catalyzed Heck-type reactions in scientific and industrial chemistry, a lot of publications and reviews have been published during the last years describing this matter under different aspects. This article presents a summary of catalytic applications of palladium complexes with phosphorus ligands containing a metallated sp3-carbon centre (“palladacycles”) or with N-heterocyclic carbene ligands in C-C and C-N coupling reactions of aryl halides including recent results of mechanistic discussions about their role in the catalytic cycle. |
| |
Keywords: | Carbenes Catalysis CC-coupling CN-coupling Palladacycles Palladium Phosphines |
本文献已被 ScienceDirect 等数据库收录! |