New nanocomposites containing metal nanoparticles, carbon nanotube and polymer |
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Authors: | Reza Sepahvand Mohsen Adeli Bandar Astinchap Roya Kabiri |
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Institution: | (1) Department of Physics, Faculty of Science, Lorestan University, Khoramabad, Iran;(2) Nanotechnology Center, Lorestan University, Khoramabad, Iran;(3) Department of Chemistry, Faculty of Science, Lorestan University, Khoramabad, Iran;(4) Lab of NMR, Faculty of Chemistry, Tabriz University, Tabriz, Iran |
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Abstract: | Metal-carbon nanotube-graft-polymer (MCNT-g-P) nanocomposites were synthesized and characterized successfully. In this work, multiwall carbon nanotubes (MWCNT) were
opened using HNO3/H2SO4 mixture and filled by metal nanoparticles such as silver nanoparticles through wet chemistry method. Then MWCNT containing
metal nanoparticles were used as macroinitiator for ring opening polymerization of ε-caprolactone and MCNT-g-P nanocomposites were obtained. Length of grafted polymer arms onto the MWCNT was controlled using MWCNT/ε-caprolactone ratio.
Structure and properties of nanocomposites were evaluated by TEM, DSC, TGA, and spectroscopy methods. |
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Keywords: | Nanocomposites Carbon nanotube Poly(caprolactone) Silver nanoparticles Nanomaterials MWCNT |
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