Stereoselective total synthesis of protected sulfamisterin and its analogues |
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| Authors: | Jana Špaková Raschmanová Miroslava Martinková Jozef Gonda Alena Uhríková |
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| Institution: | 1. Department of Organic Chemistry, Institute of Chemical Sciences, P. J. ?afárik University, Moyzesova 11, 040 01, Ko?ice, Slovakia
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| Abstract: | The stereoselective synthesis of sulfamisterin I and its unnatural analogues II and V in their protected form was achieved through a common strategy. The Wittig reaction of aldehydes VIII and IX with the C14 hydrophobic side-chain X served as the key C-C connecting transformation. Subsequent functional group inter-conversions in the coupling products XI and XX completed the total synthesis. |
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