The synthesis and stereochemistry of some isatylideneacetic acid derivatives |
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| Affiliation: | 1. Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano 10, 50019 Sesto Fiorentino, Italy;2. Istituto di Scienze e Tecnologie Molecolari (CNR-ISTM), Via Fantoli 16/15, 20138 Milano, Italy;3. Dipartimento di Chimica, Università Degli Studi di Firenze, via della Lastruccia 13, 50019 Sesto Fiorentino, Italy;4. Laboratory of Molecular Magnetism, Dipartimento di Chimica Ugo Sciff, Università Degli Studi di Firenze and INSTM RU of Firenze, Via della Lastruccia 3, 50019 Sesto Fiorentino, Italy;5. Centro di Microscopie Elettroniche (Ce.M.E.), Area di Ricerca CNR di Firenze, Via Madonna del Piano 10, 50019 Sesto Fiorentino, Italy;6. CNR-ICCOM, UOS Pisa, Area della Ricerca, Via Moruzzi 1, 56124 Pisa, Italy;1. School of Pharmacy, East China University of Science & Technology, Shanghai 200237, China;2. Shandong Keyuan Pharmaceutical Co., Ltd., Shandong Shanghe Economic Development Zone, Jinan 251601, China;1. College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, Jiangsu Province 210009, PR China;2. Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, PR China;3. State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China;1. Natural Products Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 5000 007, India;2. Chemistry Department, Sri Venkateswara University, Tirupati, Andhra Pradesh 517502, India |
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| Abstract: | The preparations of cis- and trans-1-benzylisatylidene-3-acetaldehyde, cis- and trans-1-benzylisatylidene-3-acetic acid and some derivatives are described. Structures are assigned on the basis of NMR and pKa measurements. |
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