| 蒽基修饰的新型铂基大环化合物的合成 |
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| 引用本文： | 郭大政,李登科,刘雨,李贤英,金武松,张灯青.蒽基修饰的新型铂基大环化合物的合成[J].合成化学,2020,28(2):113-117. |
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| 作者姓名： | 郭大政 李登科 刘雨 李贤英 金武松 张灯青 |
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| 作者单位： | 1. 东华大学 a. 化学化工与生物工程学院; b. 环境科学与工程学院，上海 201620 |
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| 基金项目： | 上海市自然基金资助项目 |
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| 摘 要： | 以3,5-二溴苯甲醚为起始原料，通过Suzuki偶联反应制得3,5-二吡啶苯甲醚(3)； 3经三溴化硼脱保护得到3,5-二吡啶苯酚(4)； 4进一步发生亲核取代反应得到化合物5；化合物6与5组装得到新型铂基超分子大环，其结构经1H NMR和31P NMR表征。
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| 关 键 词： | 蒽 配位键导向 自组装 铂基大环 偶联反应 合成 超分子 |
| 收稿时间： | 2018-11-01 |
Synthesis of Platinum-based Macrocyclic Compound Containing Anthracenes-modified |
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| GUO Da-zheng,LI Deng-ke,LIU Yu,LI Xian-ying,JIN Wu-song,ZHANG Deng-qing.Synthesis of Platinum-based Macrocyclic Compound Containing Anthracenes-modified[J].Chinese Journal of Synthetic Chemistry,2020,28(2):113-117. |
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| Authors: | GUO Da-zheng LI Deng-ke LIU Yu LI Xian-ying JIN Wu-song ZHANG Deng-qing |
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| Institution: | a. College of Chemistry, Chemical Engineering and Biotechnology; b. College of Environmental Science and Engineering, 1. Donghua University, Shanghai 201620, China |
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| Abstract: | 3,5-Dipyridine anisole(3) was successfully prepared from 3,5-dibromoanisole by Suzuki-coupling reaction. 3,5-Dipyridylphenol(4) was obtained through deprotection of 3, which was further treated with nucleophilic substitution to give new compound 5. Compound 6 and 5 were coupled through coordination-driven self-assembling to give an unreported organometallic macrocyclic compound. The structure was characterized by 1H NMR and 31P NMR. |
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| Keywords: | anthracene coordination-driven self-assemble platinum-based macrocycle coupling reaction synthesis supermolecule |
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