Synthesis,Crystal Structure and Fluorescent Property of [Ag_3(μ_3-I)_2(μ_2-dppm)_3]I·0.5THF·0.5H_2O |
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引用本文: | 刘玺,吴阿清,郭国聪,黄锦顺.Synthesis,Crystal Structure and Fluorescent Property of [Ag_3(μ_3-I)_2(μ_2-dppm)_3]I·0.5THF·0.5H_2O[J].结构化学,2005,24(1). |
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作者姓名: | 刘玺 吴阿清 郭国聪 黄锦顺 |
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作者单位: | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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基金项目: | This work was supported by the National Natural Science Foundation of China (20001007,20131020) and Natural Science Foundation of Fujian Province (2003I031) |
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摘 要: | 1INTRODUCTIONThepropensityforaggregationofformallyclosed-shelld10metalionsinpolynuclearcoordinationcom-plexesandsolid-statelatticeshaslongbeenrecog-nizedandexplored.Simultaneouslythesupramole-cularassemblyanddesignofmoleculeswithrichphotophysicalpropertieshavearousedgreatinter-est1~4].Sincebis(diphenylphino)methane(dppm)ligandiswidelyusedfortheformationofpoly-nuclearmetalcomplexeswithmosttransitionmetalions5~7],weutilizeddppmasabridgingligandtoreactwithsilveriodide,resultinginabicapped…
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